サイズW7.5cm×H4.35cm配置位置横11cm、縦2.5cmNNOPh2PCatalystRROHOHCatalystC6H5COCl, i -Pr2EtNRROCOC6H5OHUp to 94 % ee18214151617He678910CNOFNe1415161718SiPSClAr33343536AsSeBrKrDeveloping?novel?organocatalysts?for?highly?stereoselective?synthesis?of?organic?moleculesParticleSolidApplying?colloid?and?interface?chemistry?to?nano‐technological?and?biological?systems42Department?of?Chemistry?and?MaterialsDepartment?of?Chemistry?and?MaterialsOutlookforresearchOutlookforresearchOutlook?for?students?after?graduationOutlook?for?students?after?graduationOrganicmoleculessometimescomeinachiralformwithanenantiotopicrelationship.Iamcarryingoutresearchfocusedprimarilyonthedevelopmentofanasymmetricalcatalysttoselectivelysynthesizeonesideofachiralmolecule.Mygoalindoingsoistocreatenewcatalyststhatarehighlyselectiveandhighlyactivated,thatdonotuseraremetals,andthatcanbesynthesizedsimply.Expectedapplicationsincludethefunctionalizationofglycerin,atypeofbiomass,usingtheasymmetricesterificationreactionandtheeasysupplyofopticallyactivealcoholandamine,inadditiontothecarbon‐carbonbond‐formingreactionthatisimportantfororganicsynthesis.Graduates?have?gone?to?work?for?manufactures?of?low‐and?high‐polymer?products?and?pharmaceuticals.AssociateProfessorTetsuyaFujimotoAssociateProfessorFujimotofirstcompletedaShinshuUniversityGraduateSchoolofEngineeringresearchcoursespecializinginthestudyoffunctionalpolymers.Hisareaofresearchisorganicsyntheticchemistry,andhisworkfocusesonnewmethodsfororganicsynthesisandthedevelopmentofnewcatalysts.Aviewofthelab.Numerousreagents,solvents,andglasscontainersareusedtosynthesizethetargetorganiccompounds,yieldingsubstanceswhosestructurecanbeconfirmedusingNMR.Anasymmetricesterificationsolutiondesignedbasedonatomicprinciples,andassociatedreactions.Esterificationproceedsbydifferentiatingbetweenthetwosymmetricalhydroxylsinthediol.In?my?laboratory,?we?use?colloid?and?interfacial?science?to?study?nano‐technological?and?biological?systems.Nano‐technologicalapplications:Weareusinginterfacialforcestoproduceamonolayerofnanoparticlesatanair‐waterinterfacewithacontrolledpacking.Suchamonolayercanbeusedtoproducemagneticorsemiconductormaterials.Ourgoalistodeterminehowtocreatehigh‐qualitydevicesatlowcostbydetermining(1)theeffectsoftheparticlematerial,size,andshapeonthephysicalpropertiesofthemonolayerand(2)theforcesandfactorscontrollingthestructuringandinteractionsoftheparticlesattheinterface.Biologicalapplications:Weareresearching(1)thephysicalpropertiesofpolysaccharidesinordertoproducematerialsthatcanactaslubricantfilmsinjointsand(2)howtocontroltheinteractionsoflipidsincellmembraneswithothermoleculessoastoinhibittheiraggregation,whichcancausehealthproblemssuchasmetabolicsyndrome.Iamstudyingnano‐technologicalandbiologicalsystemsbyusingcolloidandinterfacialphysicalchemicaltechniques.Myfocusisondeterminingthefundamentalpropertiesofthesesystemsandhowtheycanbecontrolled.Inoursociety,peoplehavetothinkandmakedecisionsonnewandunknowntopicseveryday.Inmylab,wearelearninghowtothinkandmakedecisionsthoughourresearchonnewandunknownscience.Associate?ProfessorCathy?McNameeEducation:B.Sc.?(hons),?B.A.:?University?of?Queensland,?AustraliaD.Sc.:?Kyoto?University,?Japan?International?collaborations：Max?Planck?Institute?for?Polymer?Science,?GermanyResearch?Field：Colloid?and?Interface?ScienceA?particulate?monolayer?that?has?been?transferred?to?a?solid?substrateTheinteractionofglucoseorinsulinwithamodelbiologicalmembraneisdeterminedbyusingaLangmuirtroughandfluorescenceimagingtechniques.
元のページ ../index.html#43